FURTHER INVESTIGATIONS ON THE SYNTHESIS OF PURE-SILICA MOLECULAR-SIEVES VIA THE USE OF ORGANIC STRUCTURE-DIRECTING AGENTS

Several organic structure-directing agents (SDAs) that are variations of a 4,4'-trimethylenebis (N-methyl, N-R-1-piperidinium) moiety were s ynthesized and used for the synthesis of pure-silica molecular sieves. Pure-silica MTW, MFI, BEA and the MCM-41-type mesoporous materials co uld be prepared by changing only the R-1 group. When R-1 was pentyl or hexyl, MFI was crystallized, suggesting that each SDA molecule spans two channel intersections. For R-1 groups smaller than pentyl, MTW was formed. Pure-silica BEA could easily be prepared when R-1 was benzyl or cyclohexylmethyl. Numerous variations of the organics used to cryst allize BEA were explored and the features necessary to structure direc t the formation of BEA elucidated. When R-1 was either octyl or nonyl, the MCM-41-type mesoporous materials were formed, indicating that the se organics can act as surfactants. The results presented provide furt her evidence that organic molecules can serve as structure-directing a gents for the synthesis of pure-silica molecular sieves. (C) 1997 Else vier Science B.V.