F. Bruhn et al., TRACE-ELEMENT CONCENTRATIONS IN CONODONTS MEASURED BY THE BOCHUM PROTON MICROPROBE, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 130(1-4), 1997, pp. 636-640
The Proton Microprobe at Bochum has been used to study trace element c
ontents and elemental distributions in a suite of Devonian and Triassi
c conodonts, skeletal parts of marine invertebrates composed of the CO
3- and F-rich modification of apatite (francolite). The conodonts cont
ain a plethora of substituting elements (Mn, Fe, Sr, Y, light REE) at
high concentrations, and linescans and elemental maps reveal preferent
ial enrichments of many of these elements around skeletal rims. This o
bservation tends to support the concept of post-depositional chemical
alteration of the conodonts, but within an environment that still refl
ects the ambient marine conditions. Consequently, despite the high deg
ree of substitution in the apatite structure, the Sr isotope signals o
f ancient seawater may still be retained by the samples. (C) 1997 Else
vier Science B.V.