G. Garuti et al., PLATINUM-GROUP ELEMENTS AS PETROLOGICAL INDICATORS IN MAFIC-ULTRAMAFIC COMPLEXES OF THE CENTRAL AND SOUTHERN URALS - PRELIMINARY-RESULTS, Tectonophysics, 276(1-4), 1997, pp. 181-194
Platinum-group elements (PGE) and gold were analyzed by ICP-MS after t
he Ni-sulphide fire assay pre-concentration step in 44 rocks from 5 or
ogenic mafic-ultramafic massifs of the central and southern Urals. The
y comprise: (a) ring-zoned, Ural-Alaskan type bodies of the 'Pt-bearin
g belt' (Kachkanar, Tagil, Uktus); and (b) lherzolite-harzburgite comp
lexes overlain by layered wehrlite, gabbro, and diorite (Nurali, Mindy
ak) supposed to be ophiolite-type suites. Total PGE and Au contents ar
e generally higher in Ural-Alaskan type complexes compared with lherzo
lite-harzburgite complexes. Mantle-normalized PGE patterns range from
nearly unfractionated in the dunites (Pd/Ir = 0.57-3.68) to mildly and
strongly fractionated in wehrlite, clinopyroxenite, and gabbro (Pd/Ir
= 9.1-187). Exceptionally high values of Pd/Ir (761-2622) are observe
d in amphibole-rich lithologies at Kachkanar, possibly indicating a re
lationship between fractionation of the less refractory Pd and increas
ed fluid activity in the parental magma. Pronounced, positive Pt-anoma
lies, up to 20 times the mantle estimate, distinguishes the Ural-Alask
an type dunites, and progressively reduces in pyroxenites and gabbros.
In the lherzolite-harzburgite complexes of Mindyak and Nurali, layere
d wehrlites and pyroxenites, as well as rocks from the gabbro-diorite
units have fractionated PGE patterns (Pd/Ir = 2.94-92.39) and positive
Pt-anomaly as in the Ural-Alaskan complexes, Conversely, the Pt-anoma
ly is negative in the peridotites, and increases from lherzolites and
harzburgites, to dunites, similarly to residual mantle from alpine-typ
e orogenic massifs, The Pd/Ir (0.71-3.7) is higher than in ophiolites,
and resembles that of Iherzolite massifs of the western Mediterranean
, representing sub-continental mantle.Variation of the Pt-anomaly vers
us Pd/Ir in Ural-Alaskan type complexes and in the layered sequences o
verlaying lherzolite-harzburgite mantle suites is consistent with magm
atic fractionation, in which Pt behaves as a compatible element. It re
flects a progressive depletion by partial melting in mantle peridotite
s, the Pt becoming incompatible in the last stage of melting in which
Pt-poor residual dunites are formed. The positive Pt-anomaly in Ural-A
laskan type complexes is striking, and would appear as a distinctive f
eature of the parent magma, probably inherited from its mantle source.