ISOLATION AND CHARACTERIZATION OF HYDROFORMYLATION INTERMEDIATES FROMSTOICHIOMETRIC REACTIONS BETWEEN PHOSPHINOALKENES AND SOME HETEROBINUCLEAR COMPLEXES

Authors
COUTINHO KJ DICKSON RS FALLON GD JACKSON WR DESIMONE T SKELTON BW WHITE AH
Citation
Kj. Coutinho et al., ISOLATION AND CHARACTERIZATION OF HYDROFORMYLATION INTERMEDIATES FROMSTOICHIOMETRIC REACTIONS BETWEEN PHOSPHINOALKENES AND SOME HETEROBINUCLEAR COMPLEXES, Journal of the Chemical Society. Dalton transactions, (18), 1997, pp. 3193-3199
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
18
Year of publication
1997
Pages
3193 - 3199
Database
ISI
SICI code
0300-9246(1997):18<3193:IACOHI>2.0.ZU;2-E
Abstract
Some heterobimetallic acyl and mu-acyl-rhodium complexes have been iso lated from reactions of the phosphido-bridged complexes (OC)(4)M(mu-PP h2)(2)RhH(CO)(PPh3) with the phosphinoalkenes Ph2P(CH2)(n)CH=CH2 where M = Cr, Mo or W and n = 1-3. Several of the complexes have been fully characterized and their potential role as intermediates in the cataly tic hydroformylation of the parent phosphines investigated and discuss ed.