ELECTROSYNTHESIS OF AMINOTELECHELIC POLY(ACRYLAMIDE) - INITIATED BY TI(III)-NH2OH REDOX SYSTEM

Authors
PADMALATHA M SHERIGARA BS
Citation
M. Padmalatha et Bs. Sherigara, ELECTROSYNTHESIS OF AMINOTELECHELIC POLY(ACRYLAMIDE) - INITIATED BY TI(III)-NH2OH REDOX SYSTEM, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 36(8), 1997, pp. 722-724
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
36
Issue
8
Year of publication
1997
Pages
722 - 724
Database
ISI
SICI code
0376-4710(1997)36:8<722:EOAP-I>2.0.ZU;2-M
Abstract
Amino-terminated poly(acrylamide) of high molecular weight has been el ectrochemically synthesised, using titanium(III)-hydroxylamine redox s ystem in aqueous sulphuric acid phase. Polymer is characterised by spe ctral analysis and molecular weight determination. Influence of variou s parameters like, concentration of titanium(IV) sulphate, hydroxylami ne sulphate, sulphuric acid monomer, temperature and cathodic current on polymer yield has been studied. Suitable mechanism for Ti(III)-NH2O H initiated electro polymerisation of acrylamide is proposed.