SYNTHESIS, CHARACTERIZATION, AND COPPER(II)-ASSISTED P-N BOND-CLEAVAGE OF BIS(3,5-DIMETHYLPYRAZOLYL)CHLOROPHOSPHINE OXIDE AND ISOLATION ANDCHARACTERIZATION OF 3,5-DIMETHYLPYRAZOLE COMPLEXES OF COPPER(II)

Authors
BHATTACHAJEE M DATTA R
Citation
M. Bhattachajee et R. Datta, SYNTHESIS, CHARACTERIZATION, AND COPPER(II)-ASSISTED P-N BOND-CLEAVAGE OF BIS(3,5-DIMETHYLPYRAZOLYL)CHLOROPHOSPHINE OXIDE AND ISOLATION ANDCHARACTERIZATION OF 3,5-DIMETHYLPYRAZOLE COMPLEXES OF COPPER(II), Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 36(7), 1997, pp. 593-595
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
36
Issue
7
Year of publication
1997
Pages
593 - 595
Database
ISI
SICI code
0376-4710(1997)36:7<593:SCACPB>2.0.ZU;2-M
Abstract
A new mixed pyrazolyl phosphine oxide ligand, viz., bis(3,5-dimethylpy razolyl) chlorophosphine oxide (1) has been prepared from the reaction of POCl3 and 3,5-dimethylpyrazole. The compound (1) has been characte rised by elemental analysis, LR, UV-visible, H-1 and C-13 NMR spectros copy. The ligand undergoes smooth P-N bond cleavage when reacted with Cu(II) in EtOH medium and copper(II) complexes of the type [Cu(DMPZ)(2 )X-2] (DMPZ=3,5-dimethylpyrazole; X-Cl- or CH3COO-) have been isolated which have been characterised by elemental analyses, IR, UV-visible, magnetic and EPR measurements.