[4-PI-PI] CYCLOADDITIONS OF N-ACYL-THIOFORMAMIDES(2)

Authors
VALLEE Y CHAVANT PY PINET S PELLOUXLEON N ARNAUD R BARONE V
Citation
Y. Vallee et al., [4-PI-PI] CYCLOADDITIONS OF N-ACYL-THIOFORMAMIDES(2), Phosphorus, sulfur and silicon and the related elements, 120, 1997, pp. 245-258
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
120
Year of publication
1997
Pages
245 - 258
Database
ISI
SICI code
1042-6507(1997)120:<245:[CON>2.0.ZU;2-9
Abstract
Thiocarbonyl compounds, such as thioaldehydes and thioketones, are goo d dienophiles in the Diels-Alder reaction. Here we show that suitably substituted thioformamides can also be used in this reaction. A theore tical study of the [4 pi + 2 pi] cycloaddition of thiocarbonyls with b utadiene has been performed and was used to determine the needed subst ituents.