ALPHA-OXOSULFINES - NEW-GENERATION METHODS AND REACTIVITY

Authors
CAPOZZI G CORTI A MENICHETTI S NATIVI C
Citation
G. Capozzi et al., ALPHA-OXOSULFINES - NEW-GENERATION METHODS AND REACTIVITY, Phosphorus, sulfur and silicon and the related elements, 120, 1997, pp. 317-318
Citations number
2
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
120
Year of publication
1997
Pages
317 - 318
Database
ISI
SICI code
1042-6507(1997)120:<317:A-NMAR>2.0.ZU;2-V
Abstract
alpha-oxothiophthalimides 2 can be oxidised the corresponding sulfinim ides 3 with m-chloroperoxybenzoic acid. Derivatives 3 in the presence of catalytic amount of pyridine generate the alpha-oxosulfines 4 which can be trapped by diene 5 to give dihydrothiopyranes 6 as mixture of diastereoisomers. The method appears simple and general since alkyl, a ryl and hetroaryl substituted thiopthtalimides can be fruitfully used.