SYNTHESIS OF A STABLE SULFENIC ACID BY OXIDATION OF A THIOL BEARING ANOVEL BOWL-TYPE SUBSTITUENT AND ITS REDOX REACTIONS

Authors
GOTO K HOLLER M OKAZAKI R
Citation
K. Goto et al., SYNTHESIS OF A STABLE SULFENIC ACID BY OXIDATION OF A THIOL BEARING ANOVEL BOWL-TYPE SUBSTITUENT AND ITS REDOX REACTIONS, Phosphorus, sulfur and silicon and the related elements, 120, 1997, pp. 325-326
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
120
Year of publication
1997
Pages
325 - 326
Database
ISI
SICI code
1042-6507(1997)120:<325:SOASSA>2.0.ZU;2-2
Abstract
A stable sulfenic acid bearing a novel bowl-type substituent was synth esized by direct oxidation of a thiol, and its structure was determine d by X-ray crystallographic analysis. The redox reactions of a sulfeni c acid to a thiol and to a sulfinic acid, for which only those of tran sient species have been reported so far, were also demonstrated conclu sively.