STEREOSELECTIVE EPOXIDATION OF BIS-SULFINYL ALKENES AND APPLICATION TO THE ASYMMETRIC-SYNTHESIS OF ALPHA-SUBSTITUTED CARBOXYLIC-ACIDS

Authors
AGGARWAL VK WORRALL JM ALEXANDER R
Citation
Vk. Aggarwal et al., STEREOSELECTIVE EPOXIDATION OF BIS-SULFINYL ALKENES AND APPLICATION TO THE ASYMMETRIC-SYNTHESIS OF ALPHA-SUBSTITUTED CARBOXYLIC-ACIDS, Phosphorus, sulfur and silicon and the related elements, 120, 1997, pp. 351-352
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
120
Year of publication
1997
Pages
351 - 352
Database
ISI
SICI code
1042-6507(1997)120:<351:SEOBAA>2.0.ZU;2-8
Abstract
Ketene thioacetals 3 can be easily prepared in optically pure form and react diastereoselectively with metal peroxides, The resulting bis-su lfinyl oxiranes can be converted in a single step to alpha-substituted acids.