MONTMORILLONITE K10 ZNCL2 CATALYZED ALKYL DISULFIDE SUBSTITUTION-REACTIONS - PREPARATION OF THIOMETHYL DERIVATIVES FOR THE SYNTHESIS OF ORGANIC CONDUCTING MATERIALS/

Authors
CLARK PD MESHER STE PRIMAK A YAO H
Citation
Pd. Clark et al., MONTMORILLONITE K10 ZNCL2 CATALYZED ALKYL DISULFIDE SUBSTITUTION-REACTIONS - PREPARATION OF THIOMETHYL DERIVATIVES FOR THE SYNTHESIS OF ORGANIC CONDUCTING MATERIALS/, Phosphorus, sulfur and silicon and the related elements, 120, 1997, pp. 413-414
Citations number
3
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
120
Year of publication
1997
Pages
413 - 414
Database
ISI
SICI code
1042-6507(1997)120:<413:MKZCAD>2.0.ZU;2-J
Abstract
Experiments are described detailing a method for the direct introducti on of thiomethyl groups into activated benzenes, thiophene and benzo[b ]thiophene using an activated mesoporous clay to promote thiomethyl su bstitution. Elaboration of 2,3- dithiomethylbenzo[b]thiophene, a produ ct of the clay-catalyzed reaction of benzo[b]thiophene with dimethyl d isulfide, to a tetrathiafulvalene derivative is described.