STRUCTURES AND REACTION-MECHANISM OF NOVEL METAL-CARBENE COMPLEXES DERIVED FROM HYPERVALENT DIAZADISELENATHIAPENTALENES

Authors
IWASAKI F NISHIYAMA H MANABE N YASUI M MATSUMURA N
Citation
F. Iwasaki et al., STRUCTURES AND REACTION-MECHANISM OF NOVEL METAL-CARBENE COMPLEXES DERIVED FROM HYPERVALENT DIAZADISELENATHIAPENTALENES, Phosphorus, sulfur and silicon and the related elements, 120, 1997, pp. 429-430
Citations number
3
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
120
Year of publication
1997
Pages
429 - 430
Database
ISI
SICI code
1042-6507(1997)120:<429:SARONM>2.0.ZU;2-3
Abstract
Novel metal-carbene complexes (4) with a metallapentalene framework ha ve been obtained from hypervalent diazadiselenathiapentalenes (3) by t reating with Pt(PPh3)4, Pd(PPh3)4 and RhCl(PPh3)3. X-Ray investigation s revealed that the central hypervalent sulfur atom in 3 was substitut ed by a metal atom to form M-Se bonds in the resultant metallapentalen e framework.