STEREOSPECIFIC REDOX REACTION DIRECTED BY A SULFINYL GROUP

Authors
YAMAZAKI N OKAMURA M KAWAI Y MIKATA Y OHNO A
Citation
N. Yamazaki et al., STEREOSPECIFIC REDOX REACTION DIRECTED BY A SULFINYL GROUP, Phosphorus, sulfur and silicon and the related elements, 120, 1997, pp. 445-446
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
120
Year of publication
1997
Pages
445 - 446
Database
ISI
SICI code
1042-6507(1997)120:<445:SRRDBA>2.0.ZU;2-V
Abstract
Stereochemistry of reductions of a pyridinium and quinoliniums with an asymmetric sulfinyl group has been studied. Dithionite and borohydrid e prefer the face characterized by a lone pair on sulfur atom. Dihydro pyridine prefers the face characterized by a S-O bond.