The preparation of the zeolite membrane PLOT capillary column by in si
tu synthesis was described, The advantages of this new kind of column
were discussed, Some analytical application to the separation of vario
us mixtures on zeolite membrane PLOT column compared with those on the
coated zeolite PLOT column were reported, The reproducibility of the
zeolite membrane PLOT column were evaluated, It has been found that th
e zeolite membrane obtained is more homogeneous and thinner than coate
d zeolite, The zeolite membrane PLOT column can shorten the analysis t
ime, make the peak more symmetric, allow separation at lower temperatu
re and broaden the range of utilization of zeolites in GC.