HYDROTHERMAL SYNTHESIS AND CRYSTAL-STRUCTURE OF ANHYDROUS ETHYLENEDIAMINE TRIMOLYBDATE (C2H10N2)[MO3O10]

Authors
GUILLOU N FEREY G
Citation
N. Guillou et G. Ferey, HYDROTHERMAL SYNTHESIS AND CRYSTAL-STRUCTURE OF ANHYDROUS ETHYLENEDIAMINE TRIMOLYBDATE (C2H10N2)[MO3O10], Journal of solid state chemistry, 132(1), 1997, pp. 224-227
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of solid state chemistry → ACNP
ISSN journal
00224596
Volume
132
Issue
1
Year of publication
1997
Pages
224 - 227
Database
ISI
SICI code
0022-4596(1997)132:1<224:HSACOA>2.0.ZU;2-0
Abstract
Ethylenediamine trimolybdate, (C2H10N2)[Mo3O10], has been hydrothermal ly synthesized (180 degrees C, 24h, autogeneous pressure). It crystall izes in the monoclinic system (space group P2(1)/n) with a=8.0865(2) A ngstrom, b=14.4902(2) Angstrom, c=8.9306(2) Angstrom, beta=98.170(1)de grees, and Z=4. Its structure consists of hitherto unknown infinite ch ains running parallel to the a axis made up of distorted MoO6 octahedr a connected by corners, edges, and faces. Ethylenediamine cations are located between the chains and ensure the connectivity of the structur e by hydrogen bonds. (C) 1997 Academic Press.