SYNTHESIS, CIRCULAR-DICHROISM, AND ABSOLUTE STEREOCHEMISTRY OF 1,1' 4',1''-TERNAPHTHALENE COMPOUNDS/

Authors
HARADA N HIYOSHI N VASSILEV VP HAYASHI T
Citation
N. Harada et al., SYNTHESIS, CIRCULAR-DICHROISM, AND ABSOLUTE STEREOCHEMISTRY OF 1,1' 4',1''-TERNAPHTHALENE COMPOUNDS/, Chirality, 9(5-6), 1997, pp. 623-625
Citations number
10
Categorie Soggetti
Chemistry Medicinal","Pharmacology & Pharmacy
Journal title
Chirality → ACNP
ISSN journal
08990042
Volume
9
Issue
5-6
Year of publication
1997
Pages
623 - 625
Database
ISI
SICI code
0899-0042(1997)9:5-6<623:SCAASO>2.0.ZU;2-R
Abstract
Enantiopure 1,1':4',1 ''-ternaphthalene compounds were synthesized via enantioresolution of 1,1':4', 1 ''-ternaphthalene-2,2 ''-dimethanol ( 2) by the chiral phthalic acid amide method. The CD spectra of chiral 1,1':4', 1 ''-ternaphthalene compounds synthesized showed typical inte nse exciton split Cn Cotton effects, from which the absolute stereoche mistry of these 1,1':4', 1 ''-ternaphthalene compounds was unambiguous ly determined by the CD exciton chirality method. (C) 1997 Wiley-Liss, Inc.