The temperature and excitation power dependence of a bound exciton pho
toluminescence line S with a localization energy Q = 11.5 meV has been
studied in undoped and moderately Mg-doped wurtzite GaN of high resis
tivity. The data provide strong evidence that line S is due to recombi
nation of excitons bound to ionized shallow donors. The consistency of
this assignment with theoretical predictions is demonstrated. (C) 199
7 American Institute of Physics.