ELECTRONEGATIVITY - CHEMICAL HARDNESS .1.

Authors
Citation
Jl. Reed, ELECTRONEGATIVITY - CHEMICAL HARDNESS .1., The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 101(40), 1997, pp. 7396-7400
Citations number
24
Categorie Soggetti
Chemistry Physical
ISSN journal
10895639
Volume
101
Issue
40
Year of publication
1997
Pages
7396 - 7400
Database
ISI
SICI code
1089-5639(1997)101:40<7396:E-CH.>2.0.ZU;2-Z
Abstract
It has been suggested that the absolute hardness of density functional theory be identified with the chemical hardness of Pearson's principl e of hard and soft acids and bases. It is unclear whether these two ha rdnesses are actually equivalent and if no; how they are related. The problems arising from the identification uf chemical hardness with abs olute hardness are examined, as well as the problems associated with t he evaluation of absolute hardnesses, The nature of absolute hardness is explored in some derail which has given rise to an interpretation w hich is in conflict with the commonly accepted interpretations of chem ical hardness.