ABSORPTION-SPECTROSCOPY OF C-60 MOLECULES ISOLATED IN HELIUM DROPLETS

Citation
Jd. Close et al., ABSORPTION-SPECTROSCOPY OF C-60 MOLECULES ISOLATED IN HELIUM DROPLETS, Chemical physics letters, 276(5-6), 1997, pp. 393-398
Citations number
14
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
276
Issue
5-6
Year of publication
1997
Pages
393 - 398
Database
ISI
SICI code
0009-2614(1997)276:5-6<393:AOCMII>2.0.ZU;2-A
Abstract
We have recorded the electronic absorption of cold C-60 molecules embe dded in helium droplets at a temperature of approximately 0.4 K, using a beam depletion technique. We obtain highly resolved spectra in the region between 595 and 650 nm and are able to observe in detail the or igin of the electronic transitions near 638 nm. In contrast to traditi onal matrix experiments the spectra show negligible shifts and little broadening. This remarkable feature could establish the technique as a n alternative for gas-phase spectroscopy. (C) 1997 Elsevier Science B. V.