STUDY OF OXYGEN-BINDING COBALT SPECIES ON COAPO-11 MOLECULAR-SIEVE UNDER REDOX TREATMENT

Authors
WU CN CHAO KJ CHANG H LEE LJ NACCACHE C
Citation
Cn. Wu et al., STUDY OF OXYGEN-BINDING COBALT SPECIES ON COAPO-11 MOLECULAR-SIEVE UNDER REDOX TREATMENT, Journal of the Chemical Society. Faraday transactions, 93(19), 1997, pp. 3551-3553
Citations number
17
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Journal of the Chemical Society. Faraday transactions → ACNP
ISSN journal
09565000
Volume
93
Issue
19
Year of publication
1997
Pages
3551 - 3553
Database
ISI
SICI code
0956-5000(1997)93:19<3551:SOOCSO>2.0.ZU;2-#
Abstract
Under oxygen adsorption, a cobalt-O-2 species with an O-O band at 1019 cm(-1) and a paramagnetic superoxo-cobalt (Co-O-O) species with O-O a nd Co-O bands at 1048 and 467 cm(-1) have been observed on calcined an d reduced CoAPO-11 molecular sieve samples, respectively, by Raman spe ctroscopy. The stretching modes of superoxo-cobalt have also been conf irmed by O-16(2)/O-18(2) substitution.