Optical absorption measurements were performed on a series of thin GaN
epilayers. Sharp spectral features were observed due to the Is A and
B exciton transitions. Using polarization dependent absorption, the C
exciton transition was identified. A broad absorption feature was obse
rved at similar to 3.6 eV, which is attributed to indirect exciton-pho
non absorption. The excitonic structure was found to persist well abov
e room temperature. A fit to the Varshni formula yielded a temperature
dependence of E(T) = E(T = 0) -11.8 x 10(-4)T(2)(1414 + T) eV for the
A and B excitons. The exciton absorption linewidth was studied as a f
unction of temperature, indicating that GaN exhibits very large excito
n-phonon coupling. (C) 1997 American Institute of Physics.