W. Hill et V. Petrou, DETECTION OF CARIES AND COMPOSITE RESIN RESTORATIONS BY NEAR-INFRAREDRAMAN-SPECTROSCOPY, Applied spectroscopy, 51(9), 1997, pp. 1265-1268
Near-infrared Raman spectra of sound tooth substance show characterist
ic bands of its main components hydroxyapatite and collagen, and they
are virtually free of luminescence, Spectra of carious tooth substance
exhibit, in addition to the Raman bands, broadband luminescence with
an intensity similar to that of the Raman scattering. It is assumed th
at this luminescence is due to microbiological products. Raman spectra
of tooth-colored composite resin restorations differ considerably fro
m those of natural tooth substances and can therefore be used for spec
troscopic detection of such restorations.