9-MEMBERED TITANACYCLIC COMPLEXES BASED ON AN ETHYLENE-BRIDGED BIS(PHENOLATO) LIGAND - SYNTHESIS, STRUCTURE, AND OLEFIN POLYMERIZATION ACTIVITY

Authors
FOKKEN S SPANIOL TP OKUDA J SERNETZ FG MULHAUPT R
Citation
S. Fokken et al., 9-MEMBERED TITANACYCLIC COMPLEXES BASED ON AN ETHYLENE-BRIDGED BIS(PHENOLATO) LIGAND - SYNTHESIS, STRUCTURE, AND OLEFIN POLYMERIZATION ACTIVITY, Organometallics, 16(20), 1997, pp. 4240-4242
Citations number
44
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
20
Year of publication
1997
Pages
4240 - 4242
Database
ISI
SICI code
0276-7333(1997)16:20<4240:9TCBOA>2.0.ZU;2-2
Abstract
Tetravalent titanium complexes containing the ethylene-linked bis(phen olato) ligand ebmp exhibit a C-2-symmetric conformation according to s ingle-crystal X-ray structural analyses. In solution, a fluxional proc ess equivalent to an enantiomerization is detected. Upon activation, w ith. methylaluminoxane, these complexes copolymerize ethylene and styr ene with remarkably high incorporation of styrene.