NOVEL OXO-BRIDGED BLUE LUMINESCENT ORGANOALUMINUM COMPLEXES - AL-4(CH3)(6)(MU(3)-O)(2)(DPA)(2) AND AL-3(7-AZAIN)(4)(OCH(CF3)(2))(2)(CH3)(MU(3)-O) (DPA = DEPROTONATED DI-2-PYRIDYLAMINE, 7-AZAIN = DEPROTONATED 7-AZAINDOLE)

Authors
LIU W HASSAN A WANG SN
Citation
W. Liu et al., NOVEL OXO-BRIDGED BLUE LUMINESCENT ORGANOALUMINUM COMPLEXES - AL-4(CH3)(6)(MU(3)-O)(2)(DPA)(2) AND AL-3(7-AZAIN)(4)(OCH(CF3)(2))(2)(CH3)(MU(3)-O) (DPA = DEPROTONATED DI-2-PYRIDYLAMINE, 7-AZAIN = DEPROTONATED 7-AZAINDOLE), Organometallics, 16(20), 1997, pp. 4257-4259
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
20
Year of publication
1997
Pages
4257 - 4259
Database
ISI
SICI code
0276-7333(1997)16:20<4257:NOBLOC>2.0.ZU;2-W
Abstract
Two novel blue luminescent organoaluminum complexes Al-4(CH3)(6)(mu(3) -O)(2)(dpa)(2) (1) and Al-3(7-azain)(4)(OCH(CF3)(2))(2)(CH3)(mu(3)-O) (2) (dpa = deprotonated di-2-pyridylamine, 7-azain = deprotonated 7-az aindole) have been synthesized and characterized structurally. The unu sual stability of these compounds is attributed to the presence of the triply-bridging oxo ligand.