SYNTHESIS AND CHARACTERIZATION OF A DIMAGNESIATED AROMATIC COMPOUND -OLIGOMERIC DERIVATIVES OF 1,4-BIS(CHLOROMAGNESIO)-2,5-DI-TERT-BUTYLBENZENE

Authors
RECK CE WINTER CH
Citation
Ce. Reck et Ch. Winter, SYNTHESIS AND CHARACTERIZATION OF A DIMAGNESIATED AROMATIC COMPOUND -OLIGOMERIC DERIVATIVES OF 1,4-BIS(CHLOROMAGNESIO)-2,5-DI-TERT-BUTYLBENZENE, Organometallics, 16(20), 1997, pp. 4493-4496
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
20
Year of publication
1997
Pages
4493 - 4496
Database
ISI
SICI code
0276-7333(1997)16:20<4493:SACOAD>2.0.ZU;2-N
Abstract
The synthesis of 1,4-bis(chloromagnesio)-2,5-di-tert-butylbenzene was conducted by treating 1,4-bis-(chloromercurio)-2,5-di-tert-butylbenzen e with methylmagnesium chloride. The dimagnesiated compound was charac terized by hydrolysis, halogenation, and treatment with allyl bromide. NMR spectra suggest that 1,4-bis(chloromagnesio)-2,5-di-tert-butylben zene exists as a mixture of oligomers.