Kinetic effects in rapid thermal processing (RTP) are often assessed u
sing the concept of thermal budget. Although thermal budget can be def
ined in several ways, the basic premise asserts that budget minimizati
on should minimize dopant diffusion and interface degradation. The pre
sent work highlights serious shortcomings with this principle. Experim
ents show that budget minimization, according to some definitions, can
actually worsen diffusion problems rather than mitigate them. We pres
ent a straightforward framework for improving the results through comp
arison of activation energies of the desired and undesired phenomena.
This framework provides strong kinetic arguments for continued develop
ment of rapid isothermal processing and small batch fast ramp methods.