LEAD OXYACIDS AND HALIDE COMPOUNDS - CLASSIFICATION AND ANALYSIS OF CRYSTALLOGRAPHIC AND STRUCTURAL DATA

Authors
HOLLOWAY CE MELNIK M
Citation
Ce. Holloway et M. Melnik, LEAD OXYACIDS AND HALIDE COMPOUNDS - CLASSIFICATION AND ANALYSIS OF CRYSTALLOGRAPHIC AND STRUCTURAL DATA, Silicon, germanium, tin and lead compounds, 20(9), 1997, pp. 583-625
Citations number
181
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Silicon, germanium, tin and lead compounds → ACNP
ISSN journal
07921241
Volume
20
Issue
9
Year of publication
1997
Pages
583 - 625
Database
ISI
SICI code
0792-1241(1997)20:9<583:LOAHC->2.0.ZU;2-H
Abstract
This review is the last of three reviews covering the structures of le ad compounds, and covers over two hundred lead oxoacids and halides, o nly fourteen of which have the lead atom in its +4 oxidation state. On ly octahedral coordination is found for Pb(IV), but the coordination a round Pb(II) varies from trigonal to dodecahedral. Bond distances and interbond angles are correlated with covalent radii of the ligand atom s, and the effect of the non-bonded pair of valence electrons on Pb(II ) is discussed. There are examples of distortion and structural isomer ism in these derivatives.