H-1 MAS NMR-STUDY OF PROTONIC CONDUCTION IN LAYERED HNBWO6-CENTER-DOT-XH(2)O (X=1.5, 0.5)

Authors
BINESH N BHAT V BHAT SV
Citation
N. Binesh et al., H-1 MAS NMR-STUDY OF PROTONIC CONDUCTION IN LAYERED HNBWO6-CENTER-DOT-XH(2)O (X=1.5, 0.5), Solid state ionics, 86-8, 1996, pp. 609-611
Citations number
8
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
Solid state ionics → ACNP
ISSN journal
01672738
Volume
86-8
Year of publication
1996
Part
1
Pages
609 - 611
Database
ISI
SICI code
0167-2738(1996)86-8:<609:HMNOPC>2.0.ZU;2-B
Abstract
H-1 Magic Angle Spinning (MAS) NMR of layered HNbWO6 . xH(2)O (x = 1.5 , 0.5) is carried out at room temperature and at various spinning spee ds (1-12 kHz). Results on the fully hydrated sample (x = 1.5) are cons istent with the model of diffusion of H3O+ ions within the layers. In the partially dehydrated sample (x = 0.5) an exchange between the dist inctly present cage protons and H3O+ protons leads to protonic conduct ion.