THE REACTIONS OF P3N3CL5NH2 AND P3N3CL4(NH2)(2) WITH THIONYLCHLORIDE

Authors
BRINEK J TOUZIN J ALBERTI M MAREK J
Citation
J. Brinek et al., THE REACTIONS OF P3N3CL5NH2 AND P3N3CL4(NH2)(2) WITH THIONYLCHLORIDE, Chemicke listy, 91(9), 1997, pp. 626-626
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Chemicke listy → ACNP
ISSN journal
00092770
Volume
91
Issue
9
Year of publication
1997
Pages
626 - 626
Database
ISI
SICI code
0009-2770(1997)91:9<626:TROPAP>2.0.ZU;2-4
Abstract
Reaction of P3N3Cl5NH2 with thionylchloride carried out in the excess SOCl2 gives in the dependence on used reaction conditions four compoun ds P3N3Cl5NSO, P3N3Cl5NSCl2, P3N3Cl5NSNP3N3Cl5 and P3N3Cl5OP3N3Cl5. De rivatives P3N3Cl4(NH2)NSO and P3N3Cl4(NSO)(2) Can be prepared by react ion of P3N3Cl4(NH2)(2) with SOCl2 in CH2Cl2. Structures of P3N3Cl5OP3N 3Cl5 and P3N3Cl4(NH2)NSO have been solved by single crystal X-ray anal ysis.