IONIC ASSOCIATION IN LOW PERMITTIVITY MEDIA

Authors
REICHSTAEDTER L FISCHEROVA E FISCHER O
Citation
L. Reichstaedter et al., IONIC ASSOCIATION IN LOW PERMITTIVITY MEDIA, Chemicke listy, 91(9), 1997, pp. 733-734
Citations number
4
Categorie Soggetti
Chemistry
Journal title
Chemicke listy → ACNP
ISSN journal
00092770
Volume
91
Issue
9
Year of publication
1997
Pages
733 - 734
Database
ISI
SICI code
0009-2770(1997)91:9<733:IAILPM>2.0.ZU;2-3
Abstract
Lithium and sodium perchlorates in 2-butanone, ethylacetate and their mixtures have been investigated by conductance method at 25 degrees C. As the solvent permittivities decrease (from 18 to 6) the association constants of ion pairs, K-A, considerably increase. In the permittivi ty range from 12 to 6 the triple ions have been detected. Their associ ation constants, K-T, are much lower than K-A.