A CONTRIBUTION TO THE STUDY OF MECHANISM OF THE REDUCTIVE CARBONYLATION AND CARBONYLATIVE REDUCTION OF NITROAROMATES OVER A NEW CATALYTIC-SYSTEM

Authors
MACHO V KRALIK M
Citation
V. Macho et M. Kralik, A CONTRIBUTION TO THE STUDY OF MECHANISM OF THE REDUCTIVE CARBONYLATION AND CARBONYLATIVE REDUCTION OF NITROAROMATES OVER A NEW CATALYTIC-SYSTEM, Chemicke listy, 91(9), 1997, pp. 793-794
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Chemicke listy → ACNP
ISSN journal
00092770
Volume
91
Issue
9
Year of publication
1997
Pages
793 - 794
Database
ISI
SICI code
0009-2770(1997)91:9<793:ACTTSO>2.0.ZU;2-H
Abstract
A reaction scheme of the reductive carbonylation and carbonylative red uction utilising a sulfur based catalytic system has been suggested go ing from previous experimental materials(1-5) and theoretical concept. A nitrocompound may be reduced to amino compound (in the presence of water), or alkyl-N-phenyl carbamate is formed (in the presence of alka nols), or substituted ureas occur in the presence of amines.