M. Kralik et R. Fisera, THE STABILITY OF PALLADIUM CATALYSTS SUPPORTED OVER ORGANIC POLYMERS IN HYDROGENATION PROCESSES, Chemicke listy, 91(9), 1997, pp. 795-796
Catalytic tests together with an ISEC characterisation are reported on
palladium catalysts supported over DOWEXes (4 mole % crosslinked). Th
e stability of catalysts under low pressure of hydrogen (up to 0.5 MPa
) and ambient temperature is demonstrated. If higher pressure of hydro
gen and higher temperatures are applied (more than 50 degrees C), hydr
ogenolysis of the support occurs, which results in lowering of the cat
alyst activity.