Many operating mechanisms of polymer light-emitting diodes (LEDs) are
still not fully understood, among them the crucial step of recombinati
on of oppositely charged carriers to form excitons. Questions related
to this step are: What is the shape of the recombination zone and what
is the quenching loss at the metal electrode layers? An investigation
is reported in which the emission zone is directly determined by anal
yzing the polarization of the electroluminescence. It is shown that ex
citon quenching near the electrodes is a crucial parameter for the ove
rall device efficiency.