DESIGN OF STRONGLY NLO-ACTIVE MOLECULARLY-BASED FERROMAGNETS

Authors
BERNARD S YU P CORADIN T RIVIERE E NAKATANI K CLEMENT R
Citation
S. Bernard et al., DESIGN OF STRONGLY NLO-ACTIVE MOLECULARLY-BASED FERROMAGNETS, Advanced materials, 9(12), 1997, pp. 981
Citations number
15
Categorie Soggetti
Material Science
Journal title
Advanced materials → ACNP
ISSN journal
09359648
Volume
9
Issue
12
Year of publication
1997
Database
ISI
SICI code
0935-9648(1997)9:12<981:DOSNMF>2.0.ZU;2-#
Abstract
Molecule-based ferromagnets that exhibit strong second-harmonic genera tion (SHG) are presented here for the first time. The strategy for pro ducing such materials-replace the ''innocent'' bulky cations (C) in th e C[M'M(ox)(3)] family of bimetallic magnets (M' is e.g. Mn and M = Cr -III or Fe-III: the Figure shows the structure) by hyperpolarizable ca tionic chromophores-is described and X-ray, magnetic, and SHG results are reported.