Using photoelectron diffraction in the scanned energy mode we have inv
estigated the structure of ultrathin iron films on Cu(110). Up to a co
verage of at least five monolayer equivalents (5 MLE) the film grows p
seudomorphically. A quantitative analysis of the diffraction data at 1
MLE shows that the film has an island structure. The islands which co
nsist of at least two to three layers are characterised by a strong co
ntraction of the outermost Fe-Fe interlayer spacing compared to the bu
lk. (C) 1997 Elsevier Science B.V.