Om. Barabash et Tn. Legkaya, THERMODYNAMIC MODELING OF PHASE-EQUILIBRIUM IN NI-MO-C SYSTEM, Journal de chimie physique et de physico-chimie biologique, 94(9), 1997, pp. 1686-1693
Modern eutectic composites, which are worked out by now, have a very c
omplex composition. This is caused by the necessity of increasing the
number and concentration of alloying elements and is accompanied by an
essential change in concentration anc! temperature parameters of the
eutectic transformation, enlarging its temperature interval and decrea
ding directional crystallization rates. The composition region of nick
el based alloys with the molybdenum carbide, which are the most favour
able for directional crystallization, is situated on the tie-line of t
hree phase equilibrium, which is passing through the point e(0). Eutec
tic alloys gamma+ Mo2C belong to the type of skeleton eutectics and Mo
2C carbide is the phase which leads the crystallization.