PHOTOINDUCED ELECTRON-TRANSFER REACTION OF PENTAFLUOROIODOBENZENE WITH ALKENES

Authors
CAO P LONG ZY CHEN QY
Citation
P. Cao et al., PHOTOINDUCED ELECTRON-TRANSFER REACTION OF PENTAFLUOROIODOBENZENE WITH ALKENES, Molecules, 2(1), 1997, pp. 11-16
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Molecules → ACNP
ISSN journal
14203049
Volume
2
Issue
1
Year of publication
1997
Pages
11 - 16
Database
ISI
SICI code
1420-3049(1997)2:1<11:PEROPW>2.0.ZU;2-S
Abstract
Irradiation of pentafluoroiodobenzene and alkenes gave the correspondi ng adducts. The presence of single electron-transfer scavengers, (p-di nitrobenzene and t-Bu2NO) and the free radical inhibitor (hydroquinone ) suppressed the reaction. A photoinduced electron-transfer mechanism is proposed.