ALKENE EPOXIDATION CATALYZED BY IRON(III) AND MANGANESE(III) TETRAARYLPORPHYRINS COORDINATIVELY BOUND TO POLYMER AND SILICA SUPPORTS

Four tetraaryl metalloporphyrin catalysts [Fe-III, Ar = phenyl and pen tafluorophenyl; Fe-III and Mn-III, Ar = 2,6-dichlorophenyl ((FeTDCPP)- T-III and (MnTDCPP)-T-III)] have been coordinatively bonded to poly(4- vinylpyridine), and imidazole modified polystyrene (PS-Im) and silica (Si-Im). Evidence is presented that suggests that the iron(III) porphy rins are predominantly bis-ligated to the polymer supports whereas wit h (MnTDCPP)-T-III mono-ligation is preferred. On Si-Im all the complex es are mono-ligated. A fifth metalloporphyrin, the ionic manganese((II I)) 5,10,15,20-tetra(N-methyl-4-pyridyl)porphyrin (Mn(III)4MPyP), whic h binds strongly to unmodified silica. does not ligate to Si-Im. Leach ing experiments show that (FeTDCPP)-T-III is most strongly anchored to the supports. The resulting materials have been used as catalysts for the oxidation of cyclohexene and cyclooctene by iodosylbenzene. The o xidant accountabilities are good and product distributions from reacti ons under nitrogen are very comparable to those from analogous homogen eous oxidations. However, the rates of the former are markedly lower. Oxidations of cyclohexene, but not of cyclooctene, in air are biphasic . The first phase, where epoxidation predominates, is attributable to an (FeTDCPP)-T-III-catalysed oxidation by PhlO and the second. which l eads to allylic oxidation, to radical autoxidation. The best catalysts for large turnover epoxidations are (FeTDCPP)-T-III and (MnTDCPP)-T-I II on Si-Im. The causes of the lower yields with catalysts on the more flexible polymer supports are discussed. A limited study with H2O2 as the oxidant reveals that (MnTDCPP)-T-III on Si-Im, in contrast to the ionic Mn(III)T4MPyP on silica, catalyses the epoxidation of cycloocte ne.