DESIGN OF A RADICAL TRANSLOCATION STEP THROUGH 1, N (N = 5, 6, 7) HYDROGEN TRANSFERS FOR INCORPORATION INTO NEW RADICAL CASCADES

Authors
GROSS A FENSTERBANK L BOGEN S THOUVENOT R MALACRIA M
Citation
A. Gross et al., DESIGN OF A RADICAL TRANSLOCATION STEP THROUGH 1, N (N = 5, 6, 7) HYDROGEN TRANSFERS FOR INCORPORATION INTO NEW RADICAL CASCADES, Tetrahedron, 53(40), 1997, pp. 13797-13810
Citations number
61
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
40
Year of publication
1997
Pages
13797 - 13810
Database
ISI
SICI code
0040-4020(1997)53:40<13797:DOARTS>2.0.ZU;2-5
Abstract
The scope and limitations in the 1,n (n = 5, 6, 7) hydrogen transfers from homoallyl radicals of type 10 have been delineated. Encouraging r esults have notably been obtained with a dioxolane on the side chain t o promote a 1,6-H transfer and with a TBS ether to promote a 1,5-H tra nsfer. (C) 1997 Elsevier Science Ltd.