ALKOXYLATED P-PHENYLENEVINYLENE OLIGOMERS - SYNTHESIS AND SPECTROSCOPIC AND ELECTROCHEMICAL PROPERTIES

Authors
NDAYIKENGURUKIYE H JACOBS S TACHELET W VANDERLOOY J POLLARIS A GEISE HJ CLAEYS M KAUFFMANN JM JANIETZ S
Citation
H. Ndayikengurukiye et al., ALKOXYLATED P-PHENYLENEVINYLENE OLIGOMERS - SYNTHESIS AND SPECTROSCOPIC AND ELECTROCHEMICAL PROPERTIES, Tetrahedron, 53(40), 1997, pp. 13811-13828
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
40
Year of publication
1997
Pages
13811 - 13828
Database
ISI
SICI code
0040-4020(1997)53:40<13811:APO-SA>2.0.ZU;2-B
Abstract
Twenty-one n-alkoxy substituted phenylenevinylene oligomers were synth esized, varying in size, number and position of the OR groups. IR,MS a nd solubility data are presented. NMR measurements provided the molecu lar structure as well as information about conformations and molecular dynamics. UV and of cyclic voltammetric data give correlations of che mical structure (number and position of OR substituents) with separate HOMO and LUMO energies. (C) 1997 Elsevier Science Ltd.