O. Johnsen et al., LAMPROPHYLLITE AND BARYTOLAMPROPHYLLITE FROM THE TERTIARY GARDINER COMPLEX, EAST GREENLAND, Neues Jahrbuch fur Mineralogie Monatshefte, (7), 1994, pp. 328-336
Lamprophyllite and barytolamprophyllite have been found in the Tertiar
y Gardiner Complex, East Greenland, a circular complex dominated by ul
tramafic cumulates with strongly alkaline rocks such as melilite rocks
, carbonatites and phonolites, emplaced as two generations of radial d
ykes and ring dykes. Lamprophyllite and barytolamprophyllite are late
phases in pegmatitic, natrolite-rich vugs in ijolites belonging to the
second dyke generation and in related peralkaline veins and dykelets.
In addition to natrolite the lamprophyllites are typically found in a
ssociation with titanian andradite (melanite), titanite, lorenzenite a
nd pectolite. Microprobe analyses of lamprophyllite and barytolamproph
yllite from Gardiner Complex show significant variations in the Sr/Ba
ratios ranging from 4.40 to 0.26, the latter representing a barytolamp
rophyllite sample with 20.06 wt % BaO, to the authors' knowledge the h
ighest value so far recorded. The variation in the chemical compositio
n is concentrated in the M1 site accomodating the large ions Sr, Ba, K
and Na. Refined X-ray powder diffraction data is presented and a lini
ar correlation between Ba content and the asinbeta distance in the uni
t cell demonstrated.