CESIUM PENTAFLUOROTERBATE, CSTBF5

Citation
V. Gaumet et D. Avignant, CESIUM PENTAFLUOROTERBATE, CSTBF5, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1176-1178
Citations number
9
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
9
Pages
1176 - 1178
Database
ISI
SICI code
0108-2701(1997)53:<1176:CPC>2.0.ZU;2-R
Abstract
The structure of caesium terbium(IV) pentafluoride has been determined by single-crystal X-ray methods. CsTbF5 has a layered structure. The layers, which stack along the [100] direction, are built from edge- an d corner-sharing (TbF8)(4-) dodecahedra and are held together by 11-co ordinate Cs+ ions. CsTbF5 is closely related to TlZrF5.