(TRIPHENYLPHOSPHINE-P)IRIDIUM(III)-DICHLOROMETHANE SOLVATE (4 1)/

Authors
DAHLENBURG L KUHNLEIN M
Citation
L. Dahlenburg et M. Kuhnlein, (TRIPHENYLPHOSPHINE-P)IRIDIUM(III)-DICHLOROMETHANE SOLVATE (4 1)/, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1190-1192
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
9
Pages
1190 - 1192
Database
ISI
SICI code
0108-2701(1997)53:<1190:(S(1>2.0.ZU;2-F
Abstract
In the title complex, [IrH(Cl)(C18H14PS)(C-18H15P)(CO)].-0.25CH(2)Cl(2 ), the two P donors, the chloro and thiolato functions, and the carbon yl and hydride ligands are bonded in mutually trans positions. The fiv e-membered chelate ring has an envelope conformation with the metal at om deviating from the plane defined by the P and S donors and the two bridging phenylene C atoms.