(2,2,6,6-TETRAMETHYLPIPERIDINYL-1-OXY-O)COBALT(II)

Authors
DICKMAN MH
Citation
Mh. Dickman, (2,2,6,6-TETRAMETHYLPIPERIDINYL-1-OXY-O)COBALT(II), Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1192-1195
Citations number
15
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
9
Pages
1192 - 1195
Database
ISI
SICI code
0108-2701(1997)53:<1192:(>2.0.ZU;2-Q
Abstract
The structure of [Co(C5HF6O2)2(C9H18NO)(2)], measured at 173 K, is iso structural with the analogous manganese derivative at 295 K previously reported. The main differences are that in the title compound the nit roxyl O atom is disordered over two positions in a 9:1 ratio, and the M-O-N angle (where M is the metal) is about 20 degrees more acute than reported for the manganese derivative.