Citation
Es. Raper et al., DIMETHYLAMMONIUM TRICHLOROPALLADATE, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1201-1204
Citations number
15
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
9
Pages
1201 - 1204
Database
ISI
SICI code
0108-2701(1997)53:<1201:DT>2.0.ZU;2-P
Abstract
The title compound, [NH2(CH3)(2)][PdCl3], was produced as a minor prod
uct of the reaction involving 1,3-thiazolidine-2-thione and K2PdCl4 in
aqueous HCl. The structure contains [NH2(CH3)(2)](+) cations and [PdC
l3](-) anions, The anion consists of Pd-II atoms bonded to a combinati
on of bridging and terminal Cl- ions in the form of an infinite chain
of general formula [Pd(mu-Cl)(Cl)(2)](2). Each Pd-II atom is bonded in
a four-coordinate square-planar configuration. The cations are hydrog
en bonded to the [PdCl3](-) chain.