BIS(TRIPHENYLPHOSPHINE SULFIDE-S)GOLD(I) DIFLUOROPHOSPHATE(V)

Authors
LEBLANC DJ BRITTEN JF LOCK CJL
Citation
Dj. Leblanc et al., BIS(TRIPHENYLPHOSPHINE SULFIDE-S)GOLD(I) DIFLUOROPHOSPHATE(V), Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1204-1206
Citations number
16
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
9
Pages
1204 - 1206
Database
ISI
SICI code
0108-2701(1997)53:<1204:BSD>2.0.ZU;2-Y
Abstract
The cation of the title compound, [Au(C18H15PS)(2)](PO2F2), lies with the Au atom on a twofold axis, with Au-S 2.277 (2) Angstrom and S-Au-S 172.40 (12)degrees. The deviation from linearity is not caused by Au Au interactions. It may be caused by intramolecular pi-pi interactions between phenyl rings. Bond lengths and angles are normal.