2 HETEROLEPTIC COBALT(III) CYCLOPENTADIENYL DITHIOLENE COMPLEXES/

Authors
FOURMIGUE M PERROCHEAU V
Citation
M. Fourmigue et V. Perrocheau, 2 HETEROLEPTIC COBALT(III) CYCLOPENTADIENYL DITHIOLENE COMPLEXES/, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1213-1215
Citations number
22
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
9
Pages
1213 - 1215
Database
ISI
SICI code
0108-2701(1997)53:<1213:2HCCDC>2.0.ZU;2-7
Abstract
The crystal structure determinations of ,5-dimercapto-1,3-dithiole-2-t hionato)cobalt(III), [Co(C5H5)(C3S5)], and o)(eta(5)-pentamethylcyclop entadienyl)cobalt(III), [Co(C10H15)(C3S5)], show that Cp substitution does not significantly modify the geometric features of these complex es, which are characterized by a perpendicular arrangement of the plan ar Cp or Cp and (CoS2C2) moieties.