[MO(C25H22P2)(C34H33P3)(CO)]

Authors
GEORGE TA DEBORD JRD HEIER K TISDALE RC DAVIES MC HAAS EJ ROSS CR STEZOWSKI JJ
Citation
Ta. George et al., [MO(C25H22P2)(C34H33P3)(CO)], Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1251-1254
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
9
Pages
1251 - 1254
Database
ISI
SICI code
0108-2701(1997)53:<1251:[>2.0.ZU;2-R
Abstract
The crystal structure of is(2-diphenylphosphinoethyl)phenylphosphine-P ,P',P ''] [bis(diphenylphosphino)methane-P,P'] carbonylmolybdenum(0), [Mo(dpepp)(dppm)(CO)] [where dppm = Ph2PCH2PPh2 and dpepp = Ph2PCH2CH2 P(Ph)CH2CH2PPh2], is reported, In the distorted octahedral complex, th e tridentate ligand adopts a facial arrangement with the monodentate l igand trans to the central P atom, All Mo-P distances. are statistical ly dissimilar.