(Z)-1-BENZOYL-4-TERT-BUTYL-1-METHYLCYCLOHEXANE AND (Z)-4-TERT-BUTYL-1-METHYL-1-THIOBENZOYLCYCLOHEXANE

Authors
FU TY LEIBOVITCH M SCHEFFER JR TROTTER J
Citation
Ty. Fu et al., (Z)-1-BENZOYL-4-TERT-BUTYL-1-METHYLCYCLOHEXANE AND (Z)-4-TERT-BUTYL-1-METHYL-1-THIOBENZOYLCYCLOHEXANE, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1255-1256
Citations number
8
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
9
Pages
1255 - 1256
Database
ISI
SICI code
0108-2701(1997)53:<1255:(A(>2.0.ZU;2-B
Abstract
Both title molecules, C18H26O and C18H26S, contain six-membered cycloh exane rings with chair conformations, equatorial 1-methyl and 4-tert-b utyl substituents, and axial 1-benzoyl or 1-thiobenzoyl substituents, respectively. The substituent carbonyl and thiocarbonyl groups are ori ented with the O and S atoms close to axial H atoms in the cyclohexane rings, thus accounting for the observed photochemical reactivity.