SUPRAMOLECULAR ASSOCIATION OF ACID TERMINATED POLYDIMETHYLSILOXANES .1. SYNTHESIS AND CHARACTERIZATION

Authors
ABED S BOILEAU S BOUTEILLER L LACOUDRE N
Citation
S. Abed et al., SUPRAMOLECULAR ASSOCIATION OF ACID TERMINATED POLYDIMETHYLSILOXANES .1. SYNTHESIS AND CHARACTERIZATION, Polymer bulletin, 39(3), 1997, pp. 317-324
Citations number
36
Categorie Soggetti
Polymer Sciences
Journal title
Polymer bulletin → ACNP
ISSN journal
01700839
Volume
39
Issue
3
Year of publication
1997
Pages
317 - 324
Database
ISI
SICI code
0170-0839(1997)39:3<317:SAOATP>2.0.ZU;2-H
Abstract
Benzoic acid terminated polydimethylsiloxanes (PDMS) have been synthes ized by hydrosilylation of allyloxybenzylbenzoate with SiH terminated precursors followed by deprotection. These oligomers have been charact erized by H-1, C-13 and Si-29 NMR, by FTIR and by SEC in tetrahydrofur ane. Because of the flexibility and low polarity of the siloxane backb one, they are ideally suited to study the effect of hydrogen bonding o n macromolecular properties.